Angelina Jolie and Brad Pitt

It appears that marriage for Brad and Angelina is a long way off. How Brad and Angelina Met? Becoming friends while working on the movie, "Mr. & Mrs. Smith", Brad and Angelina denied having a romantic involvement while he was married to Jennifer Aniston. Their first public outing together was at the opening of the Muhammad Ali Center in Louisville, Kentucky on November 19, 2005.